人才队伍

教学科研人员

和庆钢
和庆钢 长聘副教授|博士生导师

电话: 0571-87701916

邮箱: qghe@zju.edu.cn

地址: 玉泉校区教十6107

简介

浙江大学/化学工程与生物工程学院

玉泉校区教学十楼6107室

教育工作经历:
       2022.1 – 至今         浙江大学,化学工程与生物工程学院,长聘副教授

2015.9 – 2021.12,   浙江大学,化学工程与生物工程学院,特聘研究员

2012.7 – 2015.8,     UCLA, Dept. of Molecular & Medical Pharmacology, 博士后研究员

2010.7 – 2012.6,     Lawrence Berkeley National Lab, Environmental Energy Technologies   Division, 博士后研究员

2005.9 – 2010.6,     Northeastern University (Boston), Dept. of Chemistry and Chemical Biology, 物理化学博士学位
       2002.9 – 2005.3,    上海交通大学,化学化工学院,化学工程硕士学位
       1998.9 – 2002.6,    上海交通大学,化学化工学院,化学工程与工艺学士学位

长期从事电化学能源系统、燃料电池应用技术及正电子发射计算机断层扫描(PET)核示踪试剂基础及应用研究。作为主要研究人员,完成了多项由美国能源部,美国陆军研究办公室,美国国防部等资助的重大基础科学问题项目。在电化学催化及电极反应动力学研究上取得多项创新成果。


主要研究方向

电化学工程

医学分子影像


科研主题

1. 利用电化学原位X射线吸收和衍射光谱技术,指导开发新型燃料电池电催化材料

原位X射线光谱技术(in situ XAS, XRD)是在高等同步加速器的某一阶段能量光路中置入特殊设计的电化学反应池,在改变入射光的能量(或角度)的情况下,既可获取电极材料在工作状态下的X射线吸收或衍射光谱。通过相应的图谱分析和模型计算便可获得诸如材料的电子结构,短距离和长距离原子次序,配为数,晶体结构,离子表面吸附状态等多种信息。我们主要通过in situ XAS, XRD技术,深入了解中、低温燃料电池电催化剂在真实工作状态(电压、电流等)和工作环境(酸碱度、通氧等)下的微观电子和几何结构变化。并为开发性能更高、稳定性更强、价格更低廉的新型催化材料做出指导。

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2. 利用电化学原位扫描探针显微技术,研究电化学能源转化和存储装置中界面现象

 原位扫描探针显微技术(in situ SPM)能够利用扫描探针作为工作电极,在与扫描底物之间形成电势差时,便可以在真实电化学反应状态下获取电极材料的微观形貌和结构。另外还可以测量多种离子导电材料(如导电聚合物)的离子导电通道的分布,并且对固体/固体,固体/液体界面现象进行观测。除了材料本身的性质,电化学能源转化和存储系统的综合性能与界面性质是直接相关的。基于in situ SPM技术,我们重点研究燃料电池膜电极的电子传输情况和锂离子电池中电极/电解质界面膜的生长。

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3. 正电子发射计算机断层扫描(PET)核示踪试剂电化学合成过程研究

正电子发射计算机断层扫描 (PET) 是一项分子核医学成像技术,被成功地用于肿瘤、神经系统和心血管疾病的临床诊断和治疗评价当中。由放射性同位素(如碳[11]、氟[18]等)标定的核示踪试剂的开发是这项技术在临床医学中应用的关键。目前氟[18]代脱氧葡萄糖([18F]FDG)已经取得商业化并且广泛地应用于临床(特别是肿瘤的诊断和治疗)。然而基于分子生物学及病理学的机理,不同类型的病症往往需要特殊的PET示踪剂,才能形成准确的诊断与评价。在核示踪试剂的合成过程中,人们更倾向于选择无载体的亲核取代反应(相对于亲电取代反应),以在最大程度上提高取代产物的单位核活性(specific activity)。 我们使用电化学氧化手段,利用在电极上产生的碳正离子和直接来自于回旋加速器产生的氟[18]阴离子,能够进行无载体的亲核取代反应。目前我们重点进行根据目标示踪剂的前驱体设计、电化学反应条件设置、微流体反应平台的优化、产物的分离与表征等的研究。
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专利成果

1) "一种用于定量检测单个活细菌粘附行为的原位测试系统和测试方法"

和庆钢,张硕猛,王磊,李中坚,邵文怡

中国发明专利(申请)号:2021105643869

2) "Homogeneous catalyst and anion exchange membrane fuel cell catalyst layer"
Qinggang He, Rong Ren, Xiaojiang Wang
PCT Int. Appl. (2022), WO 2022087784 A1 20220505

3) "一种均相催化剂及阴离子交换膜燃料电池催化层"

和庆钢,任荣,王晓江

中国发明专利 (2021)ZL 202011160637.9

4) "一种模块化、多功能的PET探针自动化合成系统"

和庆钢,徐洋洋,傅珠荣,赵建江,张宏,田梅

中国发明专利(2021)ZL201910094115.4

5) "一种PtNi/C合金催化剂的制备方法"

和庆钢,陈亨权,高腾洋

中国发明专利 (2020)ZL 201811469538.1

6) "一种测试质子交换膜氧气传质系数的微电极系统和方法"

和庆钢,张硕猛

中国发明专利 (2020) ZL 202010243263.0

7) "18F标记的AIE荧光/PET双模态探针及其制备方法和应用"

和庆钢,余开武,徐洋洋,张宏,田梅

中国发明专利 (2020) ZL 201910183605.1

8) "主链含ASU结构的聚合物及其制备方法和基于该聚合物的阴离子交换膜"

和庆钢,任荣

中国发明专利 (2020) ZL201810150793.3

9) "主链含溴代烷基芴的聚合物及其在阴离子交换膜中的应用"

和庆钢,任荣

中国发明专利 (2019) ZL201811314917.3

10) "含ASU侧链的聚合物及其制备方法和基于该聚合物的阴离子交换膜"

和庆钢,任荣

中国发明专利 (2018) ZL201810150795.2

11) "一种用于锂氧气电池同步辐射XRD测试的透射模式原位池"

和庆钢、朱翠翠、赵建江、唐艺钊

中国发明专利 (2018)ZL201821541825.4

12) "靶向多功能聚合物纳米探针的制备及其在含TK细胞显像中的应用"

和庆钢,任荣,张凯,张宏,田梅

中国发明专利 (2018) ZL201810059203.6

13)“阿尔兹海默症tau蛋白诊疗一体靶向药物前体合成方法”

和庆钢,任荣,张凯,张宏,田梅

中国发明专利 (2018) ZL201610946000.X

14) "一种用于半制备高效液相色谱的压力调节阀"

和庆钢、古望军、朱明桥

中国发明专利 (2018)201720449603.9

15) "一种用于放置放射性检测器探头的流动池"

和庆钢、古望军、朱明桥、田梅、张宏

中国发明专利 (2017)ZL201720591809.5

16) "一种可以进行电化学光谱实验的原位池"

和庆钢、陈亨权、赵建江

中国发明专利 (2017) 201621170358X

17) “Membrane-Electrode Structures for Molecular Catalysts for use in Fuel Cells and other Electrochemical Devices” 
J. Kerr, X. Zhu, G. Hwang, Z. Martin, Q. He, P. Driscoll, A.Weber, K. Clark
U.S. Pat. Appl. Publ. (2014), US 20140106255

18) “Synthesis of Fluorinated Radiopharmaceuticals via Electrochemical Fluorination” 
S. Sadeghi, Q. He
US Patent, PCT/US14/37731

19) “Electrochemical process for conversion of biodiesel to aviation fuels” 

S. Mukerjee, Q. He
PCT Int. Appl. (2012), WO 2012012799

20) “Highly Stable Platinum Alloy Catalyst for Methanol Electrooxidation”
S. Mukerjee, Q. He, N. Ramaswamy
PCT Int. Appl. (2011), WO 2011160022

21) “Metal Co-catalyst enhancer of electro-oxidation of ethanol”
S. Mukerjee, Q. He, P. Krtil, and K. Mancounova
PCT Int. Appl. (2011), WO 2011159314

22) “Catalyst for electrochemical applications”
E. Schwab, S. Brauninger, A. Panchenko, C. Querner, O. Unsal, M. Vogt, Q. He, N. Ramaswamy, and S. Mukerjee
PCT Int. Appl. (2010), WO 2010139596

23) “Novel electrolyte blends for enhanced mass transport in elevated temperature electrolytes”
S. Mukerjee, V. Gregoriou, Q. He
US Patent, Application No. 61/386,770, 2010

 


教学与课程

《化工原理》甲类

《化工原理》乙类

《医学分子影像》国际留学生


出版著作

1. Qinggang He and Xin Deng, "Recent Progress in Nonnoble Metal Electrocatalysts for Oxygen Reduction for Alkaline Fuel Cells" in "Electrocatalysts for Low Temperature Fuel Cells: Fundamentals and Recent Trends", Wiley-VCH, 2017

奖励荣誉

浙江大学教学大赛二等奖, 2019

浙江省分子影像重点实验室“客座教授”

《电化学》期刊编委

和庆钢 (4/10),分子影像介导的神经损伤修复与脑功能可视化研究,教育部, 高等学校科学技术进步奖,一等奖,2018 (田梅,张宏,凌代舜,和庆钢,高峰,陈巧珍,张莺,蒋韩,吴爽,丁瑶)

“浙江省转化医学协会”委员

《Chinese Chemical Letters》青年编委

“中国化工学会”会员

“浙江省化工学会”委员

和庆钢、葛君杰、任荣、肖梅玲、张硕猛、邢巍,“聚合物电解质燃料电池催化层均相催化体系的构建与研究”,2022年度中国化工学会基础研究成果奖三等奖



学术交流

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实验室介绍

 实验室以电化学作为核心技术手段,结合基于同步加速光源的X射线吸收和衍射光谱分析,以及原位扫描探针显微技术,探索电极反应过程机理和界面想象。并依此为基础,开发新型燃料电池电催化和膜电极材料,以及锂离子电池中的电解质和电极材料。实验室还致力于通过电化学方法以及其它传统合成技术手段,开发新型正电子发射计算机断层扫描(PET)核示踪探针,研究微流体化工反应中的工艺及材料问题。

实验室与中科院上海光源(同步加速器)、浙江大学分析测试中心(扫描探针显微镜)、和浙江大学医学PET中心(医用回旋加速器和PET/CT扫描仪)等单位保持长期稳定的合作,实现电化学与原位光谱和显微技术的结合,以及在核医学领域的应用。

实验室目前拥有电化学工作站、手套箱、自动化放射反应合成仪、液相色谱/质谱等装置和平台。另外,实验室同浙江大学化学工程研究所、联合化学反应工程研究所内部的若干课题组实行资源共享。


发表论文

2022年

1) Fang, Libin; Li, Haosheng; Xu, Ben Bin; Ma, Jie; Pan, Hongge; He, Qinggang; Zheng, Tianlong; Ni, Wenbin; Lin, Yue; Li, Yangmu; Cao, Yue; Sun, Che, "Latticed-Confined Conversion Chemistry of Battery Electrode", Small, PagesAhead of Print, Journal 2022, In press

2) Wang, Yanling; Zhao, Liyan; Cui, Aoran; Wang, Xiaojiang; He, Qinggang; Yang, Shikuan , "Sculpting Electrochemically Growing or Grown Microarchitectures",Small,Volume18,Issue42,Journal;Online Computer File,2203628 

3) Rong Ren, Liting Yang, Zhang Lin, Xiaoyu Li, Shuomeng Zhang, Tianlong Zheng, Duojie Wu, Jian Wang, Zidong Wei,* Wei Ding,d Ning Huang,* Meng Gu and Qinggang He*, "Construction of Symbiotic One-dimensional Ionic Channels in Cobalt-based Covalent Organic Framework for High-Performance Oxygen Reduction Electrocatalysis ", Journal of Materials Chemistry A, In press

4) Yangyang Xu, Peili Cen, Lijuan Ma, Mei Tian, Xue Zhang*, Qinghua Zhang, Kaiwu Yu, Hong Zhang*, Wangjun Gu, Qinggang He*, "Highly efficient radiosynthesis and biological evaluation of [18F]safinamide, a radiolabelled anti-parkinsonian drug for PET-imaging", ChemMedChem,  2022 Oct 19;17(20):e202200472.

5) Zhou Fang, Rong Ren, Yuqi Wang, Yue Hu, Mengyang Dong, ZhizhenYe, Qinggang He*, Xinsheng Peng*,  "Solar-driven all-in-one MOFs-based catalyst for highly efficient CO2 conversion", Applied Catalysis B: Environmental, Volume 318, 5 December 2022, 121878

6) Cen, Peili; Cui, Chunyi; Zhong, Yan; Zhou, Youyou; Wang, Zhiming; Xu, Pengfei; Luo, Xiaoyun; Xue, Le; Cheng, Zhen; Wei, Yen; He, Qinggang; Zhang, Hong; Tian, Mei *, " Visualization of Mitochondria During Embryogenesis in Zebrafish by Aggregation-Induced Emission Molecules",   Molecular Imaging and Biology, In Press        

7) Husamelden Elkawad, Yangyang Xu, Mei Tian,* Chenyang Jin, Hong Zhang,* Kaiwu Yu, Qinggang He,* "Recent advances in microfluidic devices for radiosynthesis of PET-imaging probes", Chemistry - An Asian Journal,  2022,17, e202200579 

8)郑天龙,欧明玉,徐松,毛信表*,王释一, 和庆钢*,“一体式可再生燃料电池双功能氧催化剂的研究进展”, 电化学,2022.07.20

9) Kaiwu Yu,  Jiayue Pan,  Mei Tian,* Haoke Zhang, Chentao Jin, Hong Zhang, Zhengwei Mao, Qinggang He,* "Unusual Electron Donor–Acceptor sequenced NIR AIEgen for Highly Efficient Mitochondria-Targeted Cancer Cell Photodynamic Therapy", Chemistry - An Asian Journal,2022, 17, e202200571

10) 和庆钢,李子谦,余开武,张硕猛,"将过程工程原理基础知识与前沿科学研究相结合的教学方法探索",化工高等教育,录用

11) 陈海生, 李泓, 马文涛, 徐玉杰, 王志峰, 陈满, 胡东旭, 李先锋, 唐西胜, 胡勇胜, 马衍伟, 蒋凯, 钱昊, 王青松, 王亮, 王星, 徐德厚, 周学志, 刘为, 吴贤章, 汪东林, 和庆钢, 陆雅翔, 张雪松, 李泉, 索鎏敏, 郭欢, 俞振华, 梅文昕, 秦鹏. 2021年中国储能技术研究进展[J]. 储能科学与技术, 2022, 11(3): 1052-1076

12)He, Jing; Zheng, Tianlong; Wu, Duojie; Zhang, Shuomeng; Gu, Meng; He, Qinggang*,"Insight into the determining effect of carbon support properties on anchoring active sites in Fe-N-C catalysts toward the oxygen reduction reaction" , ACS Catalysis, 2022, 12, 3, 1601–1613

13) Lutao Song,Tianlong Zheng,Lirong Zheng,Bin Lu*,Hengquan Chen,Qinggang He*, Wanzhen Zheng,Yang Hou,Jiale Lian,Yang Wu,Jian Chen,Zhizhen Ye,Jianguo Lu*, "Cobalt-doped basic iron phosphate as bifunctional electrocatalyst for long-life and high-power-density rechargeable zinc-air batteries", Applied Catalysis B: Environmental, (2022), 300, 120712

14) Rao, Qingqing; Tong, Zheming; Song, Lina; Ali, Abid; Hou, Yang; He, Qinggang; Lu, Jianguo; Gao, Xiang; Zhan, Xiaoli; Zhang, Qinghua*, "NIR-driven fast construction of patterned-wettability on slippery lubricant infused surface for droplet manipulation", Chemical Engineering Journal, 2022,428,131141




2021年

1) Tianlong Zheng, Jing He, Pingwei Cai, Xi Liu, Duojie Wu, Lutao Song, Qinggang He*, Yizhao Tang, Guangjin Wang*, Meng Gu, Jianguo Lu, Yongfeng Hu, and Zhenhai Wen*, "Enhanced Oxygen Evolution Reaction Electrocatalysis on Co(OH)2@MnO2 Decorated Carbon Nanoarrays: Effect of Heterostructure, Conductivity and Charge Storage Capability", Journal of the Electrochemical Society, 2021, 168, 114515

2) Kaiwu Yu, Rui Zhou, Yangyang Xu, Yan Zhong,  Shufang Qian,  Honghai Zhang, Haibin Shi, Yen Wei, Zhengwei Mao, Haoke Zhang, Qinggang He,* Hong Zhang, and Mei Tian*, "A Mitochondria-targeted AIEgen Labelled with 18F for Breast Cancer Cell Imaging and Therapy", Chemistry - An Asian Journal, 2021, 16(23):3963-3969

3) Shuomeng Zhang, Lei Wang, Liang Wu, Zhongjian Li*, Bin Yang, Yang Hou, Lecheng Lei, Shaoan Cheng, Qinggang He*, "Deciphering single-bacterium adhesion behavior modulated by extracellular electron transfer", Nano Letters, (2021), 21(12), 5105-5115.

4) Xiaojiang Wang, Tianlong Zheng, Yizhao Tang, Xiaoyu Li, Alexandre I. Rykov, Xuning Li, Junhu Wang, Qinggang He,* Jun Cheng, and Xue Zhang*, "The effect of tuning the coordination sphere of iron complexes for the oxygen reduction reaction in acidic media", Journal of the Electrochemical Society, (2021), 168(4), 044506

5) 徐洋洋 、任荣 、岳惠敏 、钟燕 、王晓燕 、和庆钢* 、谷岩 、 毛峥伟 、孙继红 孙继红 、田梅 、张宏*,  "制备用于间充质 制备用于间充质 制备用于间充质 干细胞成像的 FI/MRI/PETFI/MRI/PETFI/MRI/PET 三模态纳米探针", 高分子材料科学与工程, ,2021, 37(06): 154-165

6) 和晶; 王晓江; 张硕猛; 和庆钢*, “原子力显微镜在质子交换膜燃料电池表/界面现象中的应用”, 化工进展,2021, 40(6): 2993-3004

7) Fei Shen, Zhongti Sun, Qinggang He*, Jingyu Sun, Richard B Kaner* and Yuanlong Shao*, "Niobium Pentoxide Based Materials for High Rate Rechargeable Electrochemical Energy Storage", Materials Horizons,  (2021), 8(4), 1130-1152

8) Gao, Yuanxue; Wu, Shuang; Pan, Jiayue; Zhang, Kai; Li, Xiaoyi; Xu, Yangyang; Jin, Chentao; He, Xiao; Shi, Jingjing; Ma, Lijuan; Wu, Fujian; Yao, Yao; Wang, Ping; He, Qinggang; Lan, Feng*; Zhang, Hong*; Tian, Mei*, "CRISPR/Cas9-edited triple-fusion reporter gene imaging of dynamics and function of transplanted human urinary-induced pluripotent stem cell-derived cardiomyocytes", European Journal of Nuclear Medicine and Molecular Imaging, (2021), 48(3), 708-720

9) Rong Ren, Xiaojiang Wang, Hengquan Chen, Hamish Andrew Miller,* Ihtasham Salam, John Robert Varcoe, Liang Wu,* Youhu Chen, Hong-Gang Liao, Ershuai Liu, Francesco Bartoli, Francesco Vizza, Qingying Jia, and Qinggang He*, "Reshaping the Cathodic Catalyst Layer for Anion Exchange Membrane Fuel Cells: from Heterogeneous Catalysis to Homogeneous Catalysis", Angewandte Chemie International Edition,  (2021), 60(8), 4049-4054

10) Younis, Muhammad Adnan; Lyu, Siliu; Lei, Chaojun; Yang, Bin; Li, Zhongjian; He, Qinggang; Lu, Jianguo; Lei, Lecheng; Hou, Yang *, "Efficient mineralization of sulfanilamide over oxygen vacancy-rich NiFe-LDH nanosheets array during electro-fenton process", Chemosphere (2021), 268, 129272

11) Chen, Hongwen; Liu, Rumin; Wu, Yang; Cao, Junhui; Chen, Jian; Hou, Yang; Guo, Yichuan; Khatoon, Rabia; Chen, Lingxiang; Zhang, Qinghua; He, Qinggang; Lu, Jianguo*, "Interface coupling 2D/2D SnSe2/graphene heterostructure as long-cycle anode for all-climate lithium-ion battery", Chemical Engineering Journal, (2021), 407, 126973

2020年

1) Yizhao Tang,  Hao Cheng,  Qinggang He,* Hanyu Li, Yue An, Jian Xie,* and Ronghai Liu, "Highly efficient carbon-array-supported MnO2/RuO2 cathodes for lithium–oxygen batteries with spatial and induction effects", Journal of The Electrochemical Society, 2020, 167, 160536

2) Hengquan Chen, Tianlong Zheng, Qinggang He*, Longan Shang, Guangjin Wang*, Qi Wang, Xiaojiang Wang, Xiaobo Shi, Meng Gu* and Zheng Jiang, "Local coordination and ordering engineering to design efficient core-shell oxygen reduction catalysts", Journal of the Electrochemical Society, 2020, 167, 144501

3) Kaiwu Yu, Jiayue Pan, Elkawad Husamelden, Hong Zhang, Qinggang He*, Yen Wei*, Mei Tian*, "Aggregation-induced Emission Based Fluorogens for Mitochondria-targeted Tumor Imaging and Theranostics", Chemistry - An Asian Journal, 2020, 15, 3942–3960

4) Cheng Du,  Yijing Gao,  Hengquan Chen,  Ping Li,  Shuyun Zhu,  Jianguo Wang*,  Qinggang He*, and Wei Chen*, "Cu and Fe dual-atom nanozyme mimicking cytochrome c oxidase to boost the oxygen reduction reaction", Journal of Materials Chemistry A, (2020), 8(33), 16994-17001

5) Liu, Huiyuan; Qin, Jiaqi; Rockward, Tommy; Wu, Jingtian; Li, Jia; Li, Guangwei; Mao, Qing; Lv, Yang; Wang, Xiao; Zhang, Shuomeng; Shi, Weiyu; Chen, Gang; He, Qinggang; Jiang, Ying-Bing; Yu, Hongmei; Borup, Rodney L.; Wang, Yun; Song, Yujiang*, "Photo-driven growth of a monolayer of platinum spherical-nanocrowns uniformly coated on a membrane toward fuel cell applications", Journal of Materials Chemistry A, (2020), 8(44), 23284-23292

6) Shuomeng Zhang, Jujia Zhang, Zejie Zhu, Pan Liu, Fahe Cao, Jian Chen, Qinggang He*, Mei Dou, Suifei Nan, and Shanfu Lu*, "Unusual Influence of Binder Composition and Phosphoric Acid Leaching on Oxygen Mass Transport in Catalyst Layers of High-temperature Proton Exchange Membrane Fuel Cells", Journal of Power Sources, (2020), 473, 228616

7) Liu, Zhiyang; Chen, Jian*; Liu, Hao; Yan, Chizhou; Hou, Yang; He, Qinggang; Zhang, Jiujun; Hissel, Daniel, "Anode purge management for hydrogen utilization and stack durability improvement of PEM fuel cell systems", Applied Energy (2020), 275, 115110

8) Wang, Tingting; Sang, Xiahan; Zheng, Wanzhen; Yang, Bin; Yao, Siyu; Lei, Chaojun; Li, Zhongjian; He, Qinggang; Lu, Jianguo; Lei, Lecheng; Dai, Liming; Hou, Yang*, "Gas Diffusion Strategy for Inserting Atomic Iron Sites into Graphitized Carbon Supports for Unusually High-Efficient CO2 Electroreduction and High-Performance Zn-CO2 Batteries", Advanced Materials (2020), 32(29), 2002430

9) Wang, Tingting; Yang, Jian; Chen, Jiayi; He, Qinggang; Li, Zhongjian; Lei, Lecheng; Lu, Jianguo; Leung, Michael K. H.; Yang, Bin; Hou, Yang*, "Nitrogen-doped carbon nanotube-encapsulated nickel nanoparticles assembled on graphene for efficient CO2 electroreduction", Chinese Chemical Letters (2020), 31(6), 1438-1442

10) Zhu, Cuicui; Wang, Yiping; Shuai, Ling; Tang, Yizhao; Qiu, Ming*; Xie, Jian; Liu, Jia; Wen, Wen; Chen, Hengquan; Nan, Suifei; Dou, Mei; He, Qinggang*, "Remarkable improvement of cyclic stability in Li-O2 batteries using ruthenocene as a redox mediator", Chinese Chemical Letters, 2020, 31(7), 1997-2002

11) Zhao, Ye-Min; Zhang, Peng-Cheng; Xu, Chao; Zhou, Xin-You; Liao, Li-Mei; Wei, Ping-Jie; Liu, Ershuai; Chen, Hengquan; He, Qinggang*; Liu, Jin-Gang*, "Design and Preparation of Fe-N5 Catalytic Sites in Single-Atom Catalysts for Enhancing the Oxygen Reduction Reaction in Fuel Cells",  ACS Applied Materials & Interfaces (2020), 12(15), 17334-17342

12) Hengquan Chen, Guangjin Wang,* Tengyang Gao, Youhu Chen, Honggang Liao,* Xinliang Guo, Hanyu Li, Ronghai Liu, Mei Dou, Suifei Nan, and Qinggang He*, “Effect of Atomic Ordering Transformation of PtNi Nanoparticles on Alkaline Hydrogen Evolution: Unexpected Superior Activity of the Disordered Phase”,Journal of Physical Chemistry C, 2020, 124(9), 5036-5045

13) Li, Yuanyuan; Zhang, Jiawen; Zhou, Cuifang; Ling, Min; Lu, Jianguo; Hou, Yang; Zhang, Qinghua*; He, Qinggang; Zhan, Xiaoli; Chen, Fengqiu, "Flame-retardant and thermal-stable separator trapping polysulfides for lithium-sulfur battery", Journal of Alloys and Compounds (2020), 826, 154197

14) Zheng, Wanzhen; Yang, Jian; Chen, Hengquan; Hou, Yang*; Wang, Qi; Gu, Meng; He, Feng; Xia, Ying; Xia, Zheng; Li, Zhongjian; Yang, Bin; Lei, Lecheng; Yuan, Chris; He, Qinggang*; Qiu, Ming*; Feng, Xinliang*, "Atomically Defined Undercoordinated Active Sites for Highly Efficient CO2 Electroreduction", Advanced Functional Materials, 2020, 30(4): 1907658


2019年

1) Xiao, Meiling; Gao, Liqin; Wang, Ying; Wang, Xian; Zhu, Jianbing; Jin, Zhao; Liu, Changpeng; Chen, Hengquan; Li, Gaoran; Ge, Junjie*; He, Qinggang*; Wu, Zhijian; Chen, Zhongwei*; Xing, Wei*, "Engineering Energy Level of Metal Center: Ru Single-Atom Site for Efficient and Durable Oxygen Reduction Catalysis", Journal of the American Chemical Society,  2019, 141, 50, 19800-19806

2) Jin, Biyu; Yang, Lifeng; Zhang, Jiawen; Cai, Yongjie; Zhu, Juan; Lu, Jianguo; Hou, Yang; He, Qinggang; Xing, Huabin; Zhan, Xiaoli; Chen, Fengqiu; Zhang, Qinghua* , "Bioinspired Binders Actively Controlling Ion Migration and Accommodating Volume Change in High Sulfur Loading Lithium-Sulfur Batteries", Advanced Energy Materials,  2019, 9(48), 1902938 

3) Cai, Yongjie; Li, Yuanyuan; Jin, Biyu; Ali, Abid; Ling, Min; Cheng, Dangguo; Lu, Jianguo; Hou, Yang; He, Qinggang; Zhan, Xiaoli; Chen, Fengqiu; Zhang, Qinghua* , "Dual Cross-Linked Fluorinated Binder Network for High-Performance Silicon and Silicon Oxide Based Anodes in Lithium-Ion Batteries", ACS Applied Materials & Interfaces  (2019), 11(50), 46800-46807     

4) Wang, Xiaojiang; Habte, Bereket ; Zhang, Shuomeng; Yang, Houhua; Zhao, Jing; Jiang, Fangming*; He, Qinggang*, "Localized Electrochemical Impedance Measurements on Nafion Membranes: Observation and Analysis of Spatially Diverse Proton Transport Using Atomic Force Microscopy", Analytical Chemistry, (2019), 91(18), 11678-11686

5) Hu, Ye; Chen, Hengquan; Zhang, Xingmin; Wen, Wen; He, Qinggang*; He, Chao-Hong*, "Systematic Study of the Electronic, Carbon and N-Doping Effects of CoMn Oxide Composites as Bifunctional Oxygen Electrocatalysts", Journal of Physical Chemistry C, (2019), 123(36), 22130-22138

6) Rong Ren, Shuomeng Zhang, Hamish Andrew Miller*, Francesco Vizza, John Robert Varcoe*, Qinggang He*, "Facile Preparation of Novel Cardo Poly(oxindolebiphenylylene) with Pendent Quaternary Ammonium by Superacid-catalysed Polyhydroxyalkylation for Anion Exchange Membranes", Journal of Membrane Science, (2019), 591, 117320

7) Rong Ren, Shuomeng Zhang, Hamish Andrew Miller*, Francesco Vizza, John Robert Varcoe*, Qinggang He*, "Facile Preparation of an Ether-Free Anion Exchange Membrane with Pendant Cyclic Quaternary Ammonium Groups", ACS Appl. Energy Mater.,(2019), 2(7), 4576-4581

8) 古望军, 朱明乔, 李征, 任荣, 和庆钢*, 张宏*, "18F标记芳环类PET显像剂方法的研究进展", 中华核医学与分子影像杂志,2019, 8,499—503

9) Ye Hu,  Ruoou Yang, Hengquan Chen, Shaobo Han, Junhu Wang, Xiaojiang Wang, Xin Deng,  Chao-hong He, Qinggang He,* Zheng Jiang, * Meng Gu*, "One-pot approach to synthesize a highly active 3-dimensional Fe-Nx-CNTs/rGO catalyst based on the CNTs and rGO composite matrix for the oxygen reduction reaction", ChemElectroChem, 2019, 6, 504–513

10) Heyun Gu , Guangjin Wang , Cuicui Zhu, Ye Hu, Xinming Zhang, Wen Wen, Xiaowei Yang, Baofeng Wang, Xiang Gao, Xiaoli Zhan, Jingkun Li, Zi-Feng Ma*, Qinggang He*, "Correlating Cycle Performance Improvement and Structural Alleviation in LiMn2-xMxO4 Spinel Cathode Materials: A Systematic Study on the Effects of Metal-Ion Doping", Electrochimica Acta, (2019), 298, 806-817,

11) Bellini, Marco; Folliero, Maria G.; Evangelisti, Claudio; He, Qinggang; Hu, Yongfeng; Pagliaro, Maria V.; Oberhauser, Werner; Marchionni, Andrea; Filippi, Jonathan; Miller, Hamish A.; Vizza, Francesco, "A Gold-Palladium Nanoparticle Alloy Catalyst for CO Production from CO2 Electroreduction" Energy Technology, (2019), 7(4), n/a

12) Tao, Li; Qiao, Man; Jin, Rong; Li, Yan; Xiao, Zhaohui; Wang, Yuqing; Zhang, Nana; Xie, Chao; He, Qinggang; Jiang, Dechen; Yu, Gang; Li, Yafei; Wang, Shuangyin, Angewandte Chemie, International Edition, (2019), 58(4), 1019-1024


2018年

1) Tengyang Gao, Jian Yang, Masahiko Nishijima, Hamish Andrew Miller*, Francesco Vizza, Heyun Gu, Hengquan Chen, Yongfeng Hu, Zheng Jiang, Lin Wang, Ling Shuai, Ming Qiu*, Chaojun Lei, Anyun Zhang, Yang Hou*, Qinggang He*, "Evidence of the strong metal support interaction in a palladium-ceria hybrid electrocatalyst for enhancement of the hydrogen evolution reaction", Journal of The Electrochemical Society, 2018,165(14), F1147-F1153

2) Xiaojiang Wang, Yang Liu, Ying Wang, Rong Ren, Hengquan Chen, Zheng Jiang*, Qinggang He*, "Electrochemical and Spectroscopic Study of homo- and hetero-dimetallic phthalocyanines as catalysts for the oxygen reduction reaction in acidic media", ChemElectroChem, 2018, 5, 3478–3485


3) Chaojun Lei, Hengquan Chen, Junhui Cao, Jian Yang, Ming Qiu,* Ying Xia, Chris Yuan, Bin Yang, Zhongjian Li, Xingwang Zhang, Lecheng Lei, Janel Abbott, Yu Zhong, Xinhui Xia, Gang Wu,* Qinggang He,* and Yang Hou*, "Fe-N4 Sites Embedded into Carbon Nanofiber Integrated with Electrochemically Exfoliated Graphene for Oxygen Evolution in Acidic Medium", Advanced Energy Materials, 2018, 1801912


4) Xin Deng, Meiling Xiao, Ruoou Yang, Fan Guo, Hengquan Chen , Ye Hu , Yan Li, Cuicui Zhu, Yaping Deng, Zheng Jiang, Zhen Xu, Chao Gao, Qinggang He*, Junjie Ge, Yang Hou, Xingwang Zhang, Zhongwei Chen*, "The effect of CNTs on Performance Improvement of rGO Supported Fe-Nx/C Electrocatalysts for the Oxygen Reduction Reaction",Journal of The Electrochemical Society, 2018, 165(5), F401-F407                                                                             

5)Xiao, Meiling; Zhu, Jianbing; Ma, Liang; Jin, Zhao; Ge, Junjie*; Deng, Xin; Hou, Yang; He, Qinggang*; Li, Jingkun; Jia, Qingying; Mukerjee, Sanjeev; Yang, Ruoou; Jiang, Zheng; Su, Dang Sheng; Liu, Changpeng; Xing, Wei*,“Microporous Framework-Induced Synthesis of Single-Atom Dispersed Fe-N-C Acidic ORR Catalyst and Its in-Situ Reduced Fe-N4 Active Site Identification Revealed by X-Ray Absorption Spectroscopy”, ACS Catalysis,2018, 8, 2824–2832

6) 邓昕,陈亨权,和庆钢*,Fe-N-C类催化剂在碱性燃料电池中的研究进展,电化学,2018, 24(03): 235-245

7) Chen, Qing; Du, Yang; Zhang, Kai; Liang, Zeyu; Li, Jinquan; Yu, Hao; Ren, Rong; Feng, Jin; Jin, Zhiming; Li, Fangyuan; Sun, Jihong; Zhou, Min; He, Qinggang; Sun, Xiaolian; Zhang, Hong; Tian, Mei; Ling, Daishun, "Tau-Targeted Multifunctional Nanocomposite for Combinational Therapy of Alzheimer's Disease", ACS Nano, 2018, 12(2), 1321-1338


2017年

1) Hengquan Chen, Masahiko Nishijima, Guangjin Wang, Samson Khene, Mingqiao Zhu, Xin Deng, Xingmin Zhang, Wen Wen, Yu Luo, Qinggang He*, "The Ordered and Disordered Nano-Intermetallic AuCu/C Catalysts for the Oxygen Reduction Reaction: the Differences of the Electrochemical Performance", Journal of The Electrochemical Society, 164 (2017) F1654-F1661

2)"Hydrogen and Chemicals from renewable alcohols by Organometallic Electro-Reforming (OMER)" by Marco Bellini, PhD; Jonathan Filippi, PhD; Hamish Andrew Miller, PhD; Werner Oberhauser; Francesco Vizza; He Qinggang; Hansjorg Grützmacher, ChemCatChem,9 (2017) 746–750


2016年

1)Hamish A. Miller,* Marco Bellini, Werner Oberhauser, Xin Deng, Hengquan Chen, Qinggang He,* Maurizio Passaponti, Massimo Innocenti, Ruoou Yang, Fanfei Sun, Zheng Jiang, and Francesco Vizza*,“Heat treated carbon supported iron(II) phthalocyanineoxygen reduction catalysts: elucidation of the structure-activity relationship using X-ray absorption spectroscopy”,Physical Chemistry Chemical Physics,18 (2016) 33142-33151


2015年

1) "Recent progress in electrocatalysts for oxygen reduction suitable for alkaline anion exchange membrane fuel cells"

Q. He, E. Cairns

Journal of Electrochemical Society, 162 (2015) F1504-F1539 

 

2) “No-carrier-added electrochemical nucleophilic radiofluorination of aromatics”
Q. He, I. Alfeazi, S. Sadeghi
Journal of Radioanalytical and Nuclear Chemistry, 303 (2015) 1037-1040


2014年

1) “Effects of Redox Mediators on the Catalytic Activity of Iron Porphyrins towards Oxygen Reduction in Acidic Media”
Q. He, G. Wu, K. Liu, S. Khene, Q. Li, T. Mugadza, E. Deunf, T. Nyokong, and S. Chen
ChemElectroChem, 1 (2014) 1508-1515

2) “Electrochemical Nucleophilic Synthesis of Di-tert-butyl-(4-[18F]fluoro-1,2-phenylene)-dicarbonate”
Q. He, Y. Wang, I. Alfeazi, S. Sadeghi
Applied Radiation and Isotopes, 92 (2014) 52-57


2013年

1) “Electrochemical and Spectroscopic Characterization of a Dicobalt Macrocyclic Pacman Complex in the Catalysis of the Oxygen Reduction Reaction in Acid Media”,
Q. He, X. Cheng, Y. Wang, R. Qiao, W. Yang, J. Guo
Journal of Porphyrins and Phthalocyanines,17 (2013) 252-258

2) “High-Loading Cobalt Oxide Coupled with Nitrogen-Doped Graphene for Oxygen Reduction in Anion-Exchange-Membrane Alkaline Fuel Cells”,
Q. He, Q. Li, S. Khene, X. Ren, F. López-Suárez, D. Lozano-Castelló, A. Bueno-López, and G. Wu
Journal of Physical Chemistry C, 117 (2013) 8697–8707

3) “Highly Stable Pt−Au@Ru/C Catalyst Nanoparticles for Methanol Electro-oxidation”,
Q. He, B. Shyam, M. Nishijima, X. Yang, B. Koel, F. Ernst, D. Ramaker, S. Mukerjee
Journal of Physical Chemistry C, 117 (2013) 1457-1467

4) “Preparation of ceria-supported rhodium oxide sub-nanoparticles with improved catalytic activity for CO oxidation”,
V. Pérez, M. Beltrán, Q. He, Q. Wang, C. Martínez de Lecea, A. Bueno-López
Catalysis Communications, 33 (2013) 47-50

5) “Mitigating Phosphate Anion Poisoning of Cathodic Pt/C Catalysts in Phosphoric Acid Fuel Cells”,
Q. He, B. Shyam, M. Nishijima, D. Ramaker, and S. Mukerjee
Journal of Physical Chemistry C, 117 (2013) 4877–4887


2012年

1) “Scanning Probe Imaging of Surface Ion Conductance in an Anion Exchange Membrane”,
Q. He, X. Ren
Journal of Power Sources, 220 (2012) 373-376

2) “Mechanisms of Electrocatalysis of Oxygen Reduction by Metal Porphyrins in Trifluoromethane Sulfonic Acid Solution”,
Q. He, T. Mugadza, G. Hwang, T. Nyokong
International Journal of Electrochemical Science, 7 (2012) 7045-7064

3) “Dramatically Enhanced Cleavage of the C-C Bond Using an Electrocatalytically Coupled Reaction”,
Q. He, B. Shyam, K. Macounova, Petr. Krtil, D. Ramaker, S. Mukerjee
Journal of the American Chemical Society, 134 (2012) 8655-8661

4) “Molecular catalysis of the oxygen reduction reaction by iron porphyrin catalysts tethered into Nafion layers: an electrochemical study in solution and a membrane-electrode-assembly study in fuel cells”,
Q. He, T. Mugadza, X. Kang, X. Zhu, S. Chen, J. Kerr, T. Nyokong
Journal of Power Sources, 216 (2012) 67-75

5) “Electrochemical and Spectroscopic Study of Novel Cu and Fe-based Catalysts for Oxygen Reduction in Alkaline Media”,
Q. He, X. Yang, R. He, A. Bueno-López, H. Miller, X. Ren, W. Yang, and B. E. Koel
Journal of Power Sources, 213 (2012) 169-179

6) “Bridge to Fuel Cell Molecular Catalysis: 3D Non-Platinum Group Metal Catalyst in MEAs”,
X. Zhu, J. Kerr, Q. He, G. Hwang, Z. Martin, K. Clark, A. Weber, and N. Zhao
ECS Transactions, 45 (2012) 143-152


2011年

1) “Correlating Humidity-Dependent Ionically Conductive Surface Area with Transport Phenomena in Proton-Exchange Membranes”,
Q. He, A. Kusoglu, I. T. Lucas, K. Clark, A. Z. Weber, and R. Kostecki
Journal of Physical Chemistry B, 115 (2011) 11650–11657

2) “A novel CuFe-based catalyst for the oxygen reduction reaction in alkaline media”,
Q. He, X. Yang, X. Ren, B. E. Koel, N. Ramaswamy, S. Mukerjee, and R. Kostecki
Journal of Power Sources, 196 (2011) 7404-7410

3) “Effect of praseodymium oxide and cerium–praseodymium mixed oxide in the Pt electrocatalyst performance for the oxygen reduction reaction in PAFCs”,
Q. He, S. Mukerjee, S. Parres-Esclapez, and A. Bueno-Lopez
Journal of Applied Electrochemistry, 41(2011) 891-899


2010年

1) “Influence of phosphate anion adsorption on the kinetics of oxygen electroreduction on low index Pt(hkl) single crystals”,
Q. He, X. Yang, W. Chen, S. Mukerjee, B. Koel and S. Chen
Physical Chemistry Chemical Physics, 12 (2010) 12544-12555

2) “Enhanced Pt stability in MO2 (M = Ce, Zr or Ce0.9Zr0.1)-promoted Pt/C electrocatalysts for oxygen reduction reaction in PAFCs”,
Q. He, S. Mukerjee, R. Zeis, S. Parres-Exclapez, M.J. Illán-Gómez, and A. Bueno-López
Applied Catalysis A: General., 381 (2010) 54-65

3) “Electrocatalysis of Oxygen Reduction on Carbon Supported PtCo Catalysts Prepared by Water-in-Oil Microemulsions”,
Q. He, and S. Mukerjee
Electrochimica Acta, 55 (2010) 1709-1719


2009年

1) “Carbon-supported PdM (M = Au and Sn) nanocatalysts for the electrooxidation of ethanol in high pH media”,
Q. He, W. Chen, S. Mukerjee, S. Chen, and F. Laufek
Journal of Power Sources, 187 (2009) 298–304

2) “Promoting effect of CeO2 in the electrocatalytic activity of Rhodium for ethanol electro-oxidation”,
Q. He, S. Mukerjee, B. Shyam, D. Ramaker, S. Parres-Exclapez, M.J. Illán-Gómez, and A. Bueno-López
Journal of Power Sources, 193 (2009) 408-415


招聘信息

欢迎青年学者加入 “电化学反应工程”科研团队!

(招聘信息在合适人选录用信息发布前均为有效)

一、岗位名称:

博士后(2名)

二、岗位要求:

(i) 燃料电池方向
1. 获得化学、化学工程、材料科学与工程等相关专业的博士学位;
2. 具有从事电极催化材料的合成与表征,膜电极的制备、组装和测试等的研究工作经验;
3. 具备较强的X射线、红外、拉曼等光谱仪器操作和数据分析的能力;
4. 拥有独立科研能力和团队合作精神

(ii) 有机电化学合成方向
1. 获得化学、化学工程、生物工程等相关专业的博士学位;
2. 具有从事有机化学合成、或有机电化学反应、或生物制药等的研究工作经验;
3. 具备较强的LC-MS、NMR等仪器使用和数据分析的能力;
4. 拥有独立科研能力和团队合作精神

三、相关待遇:

1. 年薪12-15万人民币;
2. 按照学校政策享受住房,公费医疗及其他相关待遇;
3. 取得科研成果(论文、专利、奖项)后将获得课题组额外奖励;
4. 鼓励参加国内外的学术会议、及学术交流活动等

四、应聘联系方式:

联系人:和庆钢
E-mail: qghe@zju.edu.cn
通讯地址:浙江省杭州市浙大路38号,玉泉校区教学十楼6107室, 邮编:310027
请应聘者将个人简历、推荐人名单发送至联系人电子信箱。


合作单位及个人

上海同步辐射光源
 
Northeastern University Center for Renewable Energy Technology
 
浙江大学医学院附属第二医院核医学科


课题组成员

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课题组活动

2022年新年聚会

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2021年新年聚会

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2020年杭州大清谷烧烤

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2019新年聚会

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2018新年聚会

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