人才队伍

教学科研人员

吴素芳
吴素芳 教授|博士生导师

邮箱: wsf@zju.edu.cn

地址: 浙江大学紫金港西区和同苑1-410

简介

工学博士,教授,博士生导师。 

1992毕业于浙江大学化工系,获工学博士学位并留校工作至今。2002-2003在韩国能源研究院访问工作一年。2003在国内率先提出并开展了节能、减排的"反应吸附强化甲烷蒸汽重整制氢(简称ReSER)"新制氢技术的研究。逐步形成了以纳米CaO基CO2吸附剂、纳米CaO基镍基复合催化剂、以及复合床循环流化床反应系统为特点的ReSER制氢技术。研究以甲烷、甲醇、沼气、焦炉煤气、生物质等原料的水蒸汽重整制氢ReSER制氢技术,实现制氢过程的节能降耗以及CO2的控制排放与利用,在炼油、化工和未来氢能源领域以及二氧化碳减排和利用领域都有广阔的应用前景。 

负责课题组承担并完成国家自然科学基金项目研究三项,国家高技术863项目一项,负责承担并完成中国石油化工股份有限公司开发项目多项。共发表科研期刊论文80余篇,会议论文27篇。中国发明专利授权专利22项,美国授权专利一项。出版教材《氢能与制氢技术》。

主要研究方向

化学反应工程

镍基重整催化剂

钙基CO2吸附剂

教学与课程

氢能与制氢技术

发表论文

1、刘昊, 杨兆伟,卢尚青,吴素芳, 反应吸附强化模拟沼气蒸汽重整制氢的计算和实验研究[J]. 可再生能源,2018,36(5):633-638

2、Hao Liu, Pei Qiang Lan, Shangqing Lu, Sufang Wu, The Crystallization Kinetic Model of Nano-CaCO3 in CO2-Ammonia-Phosphogypsum Reaction System, Journal of Crystal Growth, 2018,492:114-121

3、Q .R . Lin(林启睿),Z .D .Xu(许增栋),S. F. Wu(吴素芳), Hydrogen Production via Sorption Enhanced Steam Reforming of Bio-Ethanol Using Nano Ca-Based Adsorbents(纳米钙基吸附剂脱碳强化生物乙醇蒸 汽重整制氢工艺)J. CIESC Journal(高校化工学报), 2018,32(1):161-167 ( DOI:10.3969/j.issn.1003-9015.2018.01.022)(SCI)

4、平浩梁,刘昊,吴素芳,笼状纳米CaO基吸附剂碳酸化反应动力学研究[J]. 化学反应工程与工艺,2017,33(6):487-492

5、卢尚青, 吴素芳. 纳米CaCO3孔径调控及其对碳酸化反应性能的影响[J]. 化工学报, 2018, 69(6): 2753-2758

6、S. Q. Lu, P. Q. Lan, S. F. Wu, Preparation of Nano-CaCO3 from Phosphogypsum by Gas–Liquid–Solid Reaction for CO2 Sorption, Ind. Eng. Chem. Res., 2016, 55(38), 10172-10177

7、Y. J. Fan, S. F. Wu, A graphene-supported copper-based catalyst for the hydrogenation of carbon dioxide to form methanol, J. CO2 Util., 2016, 16, 150-156

8、Y. J. Fan(樊钰佳), S. F. Wu(吴素芳),Advances in copper-based catalyst for the methanol synthesis from CO2 hydrogenation(二氧化碳加氢合成甲醇反应铜基催化剂研究进展), Chem. Ind. Eng. Prog. (化工进展), 2016, 35(z1), 159-166

9、H. L. Ping, Y. Wang, S. F. Wu,Preparation of MgO-coated Nano CaO Using Adsorption Phase Reaction Technique for CO2 Sorption,RSC Advances, 2016, DOI: 10.1039/C6RA05452H

10、H. L. Ping, S. F. Wu, CO2 sorption durability of Zr-modified nano-CaO sorbents with cage-like hollow sphere structure. ACS Sus. Chem. Eng., 2016, (DOI: 10.1021/acssuschemeng.5b01397)(SCI)

11、J. Y. Xu, X. C. Xue, S. F. Wu, Stability of the Ni-TiO2@nano CaO/Al2O3 complex catalyst used in ReSER process for hydrogen production. Int. J. Hydrogen Energy., 2016, (DOI: 10.1016/j.ijhydene.2016.03.070)(SCI)

12、S. Q. Lu, S. F. Wu, Calcination-carbonation durability of nano CaCO3 doped with Li2SO4. Chem. Eng. J., 2016, 294, 22-29.(SCI,EI)

13、X. Wu, R Wu, S. F. Wu, Kinetic study of reactive sorption-enhanced reforming of coke oven gas for hydrogen production. J. Nat. Gas Sci. Eng., 2015.10.007(SCI)

14、H. L. Ping, G. H. Xu, S. F. Wu, System optimization of cyclohexane dehydrogenation under multiphase reaction conditions using the uniform design method. Int. J. Hydrogen Energ., 2015.09.002(SCI)

15、X. C. Xue, S. F. Wu, The microstructure and stability of a Ni-nano-CaO/Al2O3 reforming catalyst under carbonation–calcination cycling conditions. Int. J. Hydrogen Energ., 2015, 40 (16), 5617-5623(SCI)

16、X. Wu, S. F. Wu, Production of high-purity hydrogen by sorption-enhanced steam reforming process of methanol. J. Energ. Chem., 2015. 24(3), 315-321(SCI)

17、X. C. Xue(薛孝宠), Y. Wang(王燕), S. F. Wu(吴素芳), Adsorption properties of coated nano CaO-based CO2 adsorbents(包覆改性纳米CaO基CO2吸附剂的反应吸附性能), Chem. Reac. Eng. Technol.(化学反应工程与工艺),2015,04, 379-384(EI)

18、S. Q. Lu(卢尚青), S. F. Wu(吴素芳), Advances in calcium carbonate thermal decomposition(碳酸钙热分解进展), CIESC J.(化工学报),2015, 08, 2895-2902 (EI)

19、H. L. Ping, S. F. Wu, Preparation of cage-like nano-CaCO3 hollow spheres for enhanced CO2 sorption, RSC Adv., 2015, 5, 65052-65057 (SCI,EI)

20、X Wu,C Wu,S. F. Wu, Dual-enhanced steam methane reforming by membrane separation of H2 and reactive sorption of CO2[J], Chem. Eng. Res. Des., 2015, 96(1), 150-7 (SCI,EI)

21、Y. Y. Shi(史余耀), P. Q. Lan(兰培强), Y. Wang(王 燕), S. F. Wu(吴素芳), Modified kinetics model of nano CaO reactions with CO2 in a CaO-based adsorben(钙基吸附剂中纳米CaO 与CO2 反应动力学模型的改进), J. Chem. Eng. Chinese Universities (高校化工学报),2015, 29(1), 96-101

22、P. Q. Lan, S. F. Wu, Mechanism for self-reactivation of nano-CaO-based CO2 sorbent in calcium looping. Fuel, 2015, 143(1), 9-15.(SCI)

23、R. Wu(吴嵘), S. F. Wu(吴素芳),Thermodynamic calculations for reactive sorption enhanced reforming of C2/C3 light hydrocarbons (反应吸附强化C2/C3烃水蒸气重整制氢反应热力学计算),CIESC J. (化工学报),2014, 65(6), 1961-1970

24、P. Q. Lan, S. F. Wu, Synthesis of a porous nano-CaO/MgO-based CO2 adsorbent, Chem. Eng. Technol., 2014, 37(4), 580-586 (SCI)

25、F. Zhang(张帆), R. Wu(吴嵘), S. F. Wu(吴素芳), Preparation of a NiO-CaO/Al2O3 sorption complex catalyst by hydrothermal precipitation method and its application in ReSER process(水热沉淀法制备NiO-CaO/Al2O3复合催化剂及其在ReSER制氢中的应用), J. Chem. Eng. Chinese Universities (高校化工学报), 2014, 28(5), 985-991 (EI)

26、F. Zhang(张帆), S. F. Wu(吴素芳), Investigation on synthesis conditions of NiO-CaO/Al2O3 sorption complex catalyst by hydrothermal precipitation method(水热沉淀法制备Ni-CaO/Al2O3复合催化剂工艺条件的考察), Chem. Reac. Eng. Technol. (化学反应工程与工艺), 2014.30(5), 428-431(EI )0.

27、F. Zhang, Q. Tang, S. F. Wu. Preparation of a mesoporous sorption complex catalyst and its evaluation in reactive sorption enhanced reforming. J. ZJU Sci. (A), 2013, 12, 915-922.( SCI, EI )

28、R Wu, S. F. Wu The ReSER-COG process for hydrogen production on a Ni–CaO/Al2O3 complex catalyst. Int. J. Hydrogen Energ., 2013,38:11818-11825.( SCI, EI )

29、Y Wang, Y. Q. Zhu,S. F. Wu,A new nano CaO-based CO2 adsorbent prepared using an adsorption phase technique, Chem. Eng. J., 2013, 218, 39-45.( SCI, EI )

30、H. Z. Feng, P.Q, Lan, S. F. Wu, A study on the stability of a NiO-CaO/Al2O3 complex catalyst by La2O3 modification for hydrogen production. Int. J. Hydrogen Energ., 2012,37(19), 14161-14166 ( SCI, EI )

31、Q. Tang(唐琪),S. F. Wu(吴素芳),The effect of CaO content on sorption performance of nano CaO based CO2 adsorbent(CaO含量对纳米CaO/Al2O3吸附剂性能的影响), J. Chem. Eng. Chinese Universities (高校化学工程学报),2012,26(1), 31-37

32、S. F. Wu, P. Q. Lan, A kinetic model of nano-CaO reactions with CO2 in a sorption complex catalyst, AIChE J. 2012, 58(5),1570-1577

33、Y. Q. Zhu, S. F. Wu , X. Q. Wang. Nano CaO grain characteristics and growth model under calcination, Chem. Eng. J., 2011,175(15), 512-518 (SCI, EI)

34、S. F. Wu, M. Z. Jiang. Formation of a Ca12Al14O33 nanolayer and its effect on the attrition behavior of CO2-adsorbent microspheres composed of CaO nanoparticles, Ind. Eng. Chem. Res. 2010, 49(23), 12269–12275(SCI, E)

35、S. F. Wu, L. L. Wang,Improvement of the stability of a ZrO2-modified Nienano-CaO sorption complex catalyst for ReSER hydrogen production,Int. J. Hydrogen Energ., 2010, 35(13), 6518-6524(SCI, EI)

36、S. F. Wu, Y. Q. Zhu. Behavior of CaTiO3/Nano-CaO as a CO2 reactive adsorbent, Ind. Eng. Chem. Res. 2010,49(6), 2701-2706(SCI, EI)

37、S. F. Wu, L. B. Li, Y. Q. Zhu,X.Q. Wang, A micro-sphere catalyst complex with nano CaCO3 precursor for hydrogen production used in ReSER process, Eng. Sci., 2010,8(1):22-26

38、Q. Shi(师琦), S. F. Wu(吴素芳), M. Z. Jiang(蒋明哲), Q. H. Li(李清辉),Reactive sorption-decomposition kinetics of nano Ca-based CO2 sorbents(纳米钙基CO2吸附剂反应吸附与分解动力学),CIESC J. (化工学报),2009,60(3):641-648 (EI)

39、Q. Shi(师琦), S. F. Wu(吴素芳), Properties of SiO2 coated nano SiO2/CaCO3 sorbents by precipitation method(沉淀法SiO2包覆纳米CaCO3吸附剂性能),CIESC J. (化工学报),2009, 60(2), 507-513 (EI)

40、Q. Q. Wang(王清清), S. F. Wu(吴素芳), L.L. Wang(王璐璐), The desulfurization properties and mechanism of Ni2+ modified zeolites for desulfurization of model diesel(Ni 离子改性分子筛模拟柴油吸附脱硫的性能与机理), J. Chem. Eng. Chinese Universities (高校化学工程学报), 2008, 22(6), 1049-1054(EI)

41、S. F. Wu, Qing. H. Li, Jong. N. Kim ,Kwang. B. Yi,Properties of nano CaO/Al2O3 CO2 sorbent, Ind. Eng. Chem. Res.2008, 47(1) 180-184 (SCI, EI)

42、S. F. Wu, T. H. Beum, J. I. Yang, and J.N. Kim, Properties of Ca-based CO2 sorbent using Ca(OH)2 as precursor, Ind. Eng. Chem. Res. 2007,46:7896-7899(SCI, EI)

43、M. Li(李明),S. F. Wu(吴素芳),H. F. Li(李洪峰),Study on macro-kinetics of preparation of tethyl isobutyl ketone via dehydrogenation of methyl isobutyl carbinol (MIBC脱氢制备MIBK宏观动力学研究), J. Chem. Eng. Chinese Universities (高校化学工程学报), 2007, 21(3), 520-524(EI)

44、Q. H. Li(李清辉),S. F. Wu(吴素芳),Factors of CO2 adsorption ratio of CO2 sorbent used in the adsorption enhanced reaction to producing hydrogen from nature gas (用于天然气吸附强化制氢的CO2吸附剂吸附率影响因素), ZheJiang Chem. Ind.(浙江化工), 2007, 38(8), 4-6

45、J. He(贺隽),S. F. Wu(吴素芳),The characteristics of sorption enhanced steam methane reforming for hydrogen production on a complex catalyst(吸附强化的甲烷水蒸汽重整制氢反应特性), Chem. Reac. Eng. Technol.(化学反应工程与工艺),2007, 23(5), 470-373

46、R. Wu(吴嵘), S. F. Wu(吴素芳), Performance of nano-CaCO3 coated with SiO2 on CO2 adsorption at high temperature(包硅改性纳米碳酸钙应用于高温CO2吸附的性能). CIESC J. (化工学报), 2006, 57(7), 1722-1726 (EI)S. F. Wu(吴素芳), T. H. Beum, J. I. Yang, J. N. Kim, The characteristics of a sorption-enhanced steam-methane

47、reaction for the production of hydrogen using CO2 sorbent. CIESC J. (化工学报英文版), 2005, 13(1), 43-47 (EI)

专利成果

1、吴素芳,杨兆伟,平浩梁,利用氧化钙反应吸附二氧化碳强化沼气水蒸气连续重整制氢的方法,中国发明专利,ZL201510429092

2、吴素芳,王燕,薛孝宠,一种表面包覆改性的纳米氧化钙基CO2吸附剂及其制备方法,中国发明专利,ZL2014101535278

3、S. F. Wu,P. Q. Lan, Method for preparing a nano calcium carbonate slurry from waste gypsum as calcium source, the product use and thereof ,US 8846562(美国授权专利),2014,Sep.30

4、吴素芳,吴翔,一种吸附强化的甲醇水蒸气重整制氢方法及装置,中国发明专利, ZL201310198209.9

5、吴素芳,薛孝宠,王樟茂,吴翔,徐金炎,一种流化-固定复合床反应吸附强化甲烷水蒸气重整制氢的装置及方法,中国发明专利,ZL201310241587.0

6、吴素芳,兰培强,一种以废石膏为钙源制备纳米碳酸钙浆料的方法、产品及应用,中国发明专利,ZL201310631224.8

7、吴素芳,吴成,汪燮卿,一种脱碳和脱氢双重强化甲烷水蒸汽重整制氢的方法及装置,中国发明专利,ZL201210133963.X

8、吴素芳,兰培强,一种以废石膏为钙源制备纳米碳酸钙浆料的方法、产品及应用,中国发明专利,ZL201210133971.4

9、吴素芳,史余耀,吴嵘,薛孝宠,王燕,一种用于循环流化床的微球纳米CaO基CO2吸附剂的制备方法、产品及应用,中国发明专利,ZL20121012247205

10、吴素芳. 唐琪,扩孔氧化镍—氧化钙/氧化铝复合催化剂及其制备和应用,中国发明专利, ZL201110172085.8

11、吴素芳,蒋明哲,一种制备耐磨纳米氧化钙基二氧化碳反应吸附剂的方法,中国发明专利, ZL201010515871.9

12、吴素芳,朱艳青,表面包覆CaTiO3的氧化钙基CO2吸附剂的制备,中国发明专利,ZL200910096765.9

13、吴素芳,师琦,二氧化硅改性的纳米钙基二氧化碳吸收剂的制各方法,中国发明专利,ZL 200810062651,8

14、吴素芳,秦统福,周洪义,王樟茂,汪燮卿,采用固定床吸附强化的甲烷水蒸汽重整制氢工艺及装置,中国发明专利,ZL200610155120.4

15、吴素芳,焦炉煤气吸附强化的催化反应制氢方法及装置,中国发明专利,ZL2006101550818

16、吴素芳,汪燮卿,王樟茂,采用循环流化床的吸附强化甲烷水蒸汽重整制氢工艺及装置,中国发明专利,ZL2006100653567.0

17、吴素芳,贺隽,汪燮卿,用于甲烷水蒸汽重整制氢的复合催化剂及制备方法和应用, 中国发明专利,ZL200610052788.6

18、吴素芳,吴嵘,含硅纳米氧化钙高温二氧化碳吸附剂和该吸附剂的制备方法以及在制氢工业中的应用,中国发明专利,ZL200510060911.4

19、吴素芳,李明,甲基异丁基醇气相催化脱氢铜系催化剂、制备方法及应用方法,中国发明专利,ZL200510061223.X

出版著作

吴素芳 编著,《氢能与制氢技术》,杭州,浙江大学出版社,第二版,2021.

吴素芳,《氢能与制氢技术》,浙江大学出版社,2014-09-01.